dtgreene: Final Fantasy 5 is, by far, the best game in the series.
I also like 1, 2, and 3, though those games, particularly 2, might be a bit harder to get into.
Cambrey: I couldn't get into any of them. I found them dull and boring. The class system was fun indeed, but that was the only thing that really got me going. The series would have never survived if it weren't for the changes they made after FF5.
The job system (and the game consistently calls it a "job" system), combined with better enemy variety than in FF3, is more than enough to carry the game.
I disagree that the series would have never survived if they hadn't made the changes. In fact, the series, as it existed prior to FF6, was effectively killed by the changes that made it no longer recognizable.
_Auster_: - Final Fantasy X - any version (or the PS2 versions if you don't want surprise superbosses halfway through the game)
Except that the International PS2 version (released everywhere except the US, though note that Japan got both original and International) has those surprise superbosses.
(Also, I note that FFX's postgame content, particularly those superbosses, is poorly designed.)