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I was just on a mission to capture an alien officer. I shot down a corvette and was given notification that there was an alien officer on board. I had 4 soldiers just outside the door, 2 were shield and 2 behind them were assault.

Lo and behold the officer opens the door! The perfect chance to stun with my two shield guys with their stun weapons!

But it was all for naught as the assault guys both reaction fire and gun him down!