Judging by the graphics, could 9 be from Gothic 3?

Long shot, but might 31 then be Grumznar?

There are two version floating around and I honestly don't remember myself which one is correct, so I'm counting this one valid.

Is 18 named Beleth?

9 isn't from Gothic 3, 49 isn't from Two Worlds (2), and this
is also incorrect.

MWAHAHAHAH!!!
When I saw that bad 3D figure I had an inkling... anyway
24. Ishmael, of The Wheel of Time.

Is 28 Zaks from the Dizzy games? Magic Land Dizzy, I suspect that screenshot's from.

Unofficial points tally:

grviper: 22
Zchinque: 12
DodoGeo: 7
Dragobr: 6
ShogunDarius: 4
wlmiv: 3
oasis789: 3
QuadrAlien: 2
ne_Zavarj: 2
Lexor: 2
reaver894: 1
Garugo: 1
nmillar: 1

34 points left.

I think I've more or less added all I can. Some of the pictures look somewhat familiar, but not amount of braning or googling seem to come up with anything. So hopefully 12 points will be enough for a top 4. :)

37 is Terexin from Hocus Pocus.

Annoyingly noticed this one immediately after my last post. :P

^ that was the one I was afraid could pose some problems. Good you proved me wrong :P

~~
Surprisingly, there are several not-yet-guessed GOGs here.

45. Pools of Darkness - Elminster (Knew it was him, but couldn't figure out the game)

Just bumping it for a night.
(or what passes for a night here, anyway)

You've got to be kidding... That's some deeply-hidden guy.
19. Saros Shadow Follower, of Dungeon Master 2: Skullkeep
Thanks to Return to Chaos, the remake that works...

5: King Brona (Shannara)
42: Sidi (Return to Krondor)

22. Crodo, from Might & Magic... err, World of Xeen, ye-es, World..

Now to figure out where I've definitely seen the geezer from 26