These games won't work because they are DOS games and are bundled with a 32-bit version of the Boxer DOS emulator. Catalina does not support 32-bit software.
Unfortunately, Boxer does not seem to have been updated since 2016, and is still 32-bit.
It shouldn't be too terribly difficult to get these games working. You would just need to grab the game files from the app package, and grab a 64-bit build of DOSBox (the underlying emulator Boxer is based on). I might play with it when I get some time.
The actual game files are located in STAR WARS™ Rebel Assault.app/Contents/Resources/Star Wars Rebel Assault.boxer/C Star Wars - Rebel Assault.harddisk/REBEL/
There is also a "DOSBox Preferences.conf" file in the Rebel Assault.harddisk directory which would set up DOSBox to use the same settings Boxer is using.
Hopefully GOG repackages these games for Catalina soon.