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After the intro movie (the one that starts out with "In the year 1999-"), I always CTD, and get a "RainbowSix.exe has stopped working" message. I've heard that there's an issue with Windows 7 64-bit and ATI cards together. If that is the case, am I just screwed, or is there some way I can fix this?
Check out my solution - "AMD/ATI Cat 13.4 Solution" - that I just posted in this forum. I cannot post the link yet. It may fix your problem.

Good luck.