orcishgamer: A lot of GOGs will fit on a single 4.7 GB DVD-R+/-, so you don't waste too much space separate a lot of your small GOGs into directories of roughly that total filesize and burn away. May I also suggest a Synology NAS (stands for Network Attached Storage) for quickly accessing files you don't have on your main machine. They aren't that cheap but you can get a small one set up for 200-300 dollars and it's actually a very good investment for anyone who has multiple machines at home (beats futzing with discs too).
You should still do disc backup (maybe even offsite) even if you get a NAS.
As an alternative to a NAS, a USB hard drive also does the trick. I have my installers and add-ons backed up to the USB drive, and installed the older and less drive-intensive games on that drive, as well. Works great for the DOSBox games that you can run anywhere, as would installing them to a thumb drive. The NAS is nice if you want to access a bunch of other stuff on multiple PCs, though, something a USB drive isn't particularly good at.