-The Nameless one from Torment. An enigmatic character.
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Berengar and Geralt of Rivia, both from The Witcher. I like their history and I find them charismatic.
-Gelu and Sandro, from HoMM3. They are powerful and I like their backstory.
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Cutter Slade from Outcast. He has a lot of charisma and I like some of his punchlines.
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King Trode from Dragon Quest 8. He's amusing.
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Kiefer from Dragon Quest 7. He's an entertaining character with a interesting destiny. Overall, there are tons of characters from the DQ series that I like.
Adding links is a real chore on this forum.