I'm not sure what you're asking, so I'll give you two answers:
If you're not familiar with how to navigate the files on your computer (I don't mean to be condescending at all with this, trust me, I've been there before and know how it feels),you should be able to go to something called "File Explorer" and then copy and paste "C:\Users\*YourUserNameHere*Documents\The Witcher 3" into the top bar, replacing "*YourUserNameHere*" with whatever your login name for your profile on your computer is. The files user.settings and user.settings.bak should presumably be somewhere in there, just delete them from there.
If you mean that you got there and don't see those files at all, perhaps you could provide a screenshot or somebody else can help you.