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I heard that GOG's version of Saints Row 2 has been fixed and optimized and I was wondering if I can somehow redeem my Steam copy on this site.
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Currently the only games that can be redeemed from other sources on GOG are listed here

The Witcher 1 & 2 can also be redeemed from certain sites as well.
The best way is to buy GOG games, so you can cancel your Steam account.