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MOO 1 and 2 are hands down my favourite 4x games, and possibly even strategy games, ever made. The first one was one of those games that really got me into PC gaming in the first place. Even after all this time they are still jus as fresh and fun as when they first came out. I can't tell you how many sleepless nights I had in college playing "just one more turn" when I should have been studying.
Theseare games that reward you for thinking creatively. Watching your empire grow, and potentially outgrow those of your enemies, is an amazing feeling. I guarantee that once you get hooked you will play them again and again, thanks to the sandbox style game set up.