sanscript: I always try to use absolute paths with zero spaces in my scrips as to avoid any confusion, which makes moving it around easier as it would run anywhere. It will make the command lines longer but easier to catch things.
Like
python f:\gogrepoc.py download f:\gog\ -os windows -lang en -skipextras
It depends how you use it.
Me (and I think the OP) are always running gogrepoc.py script from within the same USB hard drive where it downloads the installers too.
So on that USB hard drive I have e.g. a subdirectory \GOG\ or \gogrepoc\ or whatever, to which I always go first to run the actual script because nothing will happen if I type "gogrepoc.py" anywhere else. That is the only place where the script is and runs.
And below that subdirectory I have the GOG\ subdirectory which contains the installers.
For me running e.g. "python gogrepoc.py download gog\" always works because I am always running the script from that same location on that same USB hard drive, under which the gog subdirectory with the installers always is. I don't need to have gogrepoc "installed" on several PCs, it always follows with the installers, no matter to which PC I connect it to (that PC must have python installed though, and the needed python modules).
It even works on Linux machines, but there I need to use the commands a bit differently, like "python3 gogrepoc.py download ./GOG/". That doesn't matter, I normally use a "linuxgog.sh" script that is on that same USB drive on Linux, while on Windows I use a windowsgog.bat batch file that have commands suitable for Windows.
If I used absolute paths with drive letters, it would often fail if that USB hard drive for some reason got a different drive letter when I connect it to a new PC.
windowsgog.bat:
python gogrepoc.py update -lang en -os windows
python gogrepoc.py download gog\
python gogrepoc.py clean gog\
python gogrepoc.py verify gog\
linuxgog.sh:
python3 gogrepoc.py update -lang en -os windows
python3 gogrepoc.py download ./GOG/
python3 gogrepoc.py clean ./GOG/
python3 gogrepoc.py verify ./GOG/