I don't currently have a Mac but I can confirm that Catalina definitely killed 32-bit support, so if they aren't working now, it's due to that, so you need to go back to Mojave (or install Mojave on Parallels or dual boot with Linux/Windows), and install your 32 bit games/apps there.
About GOG games, I believe it's up to the devs if they release their games 32 or 64 bit here on GOG. Supposing some are 32 bit, it's up to them to update their games as well. :/