Killing random Brotherhood paladin won't work since there is no correlation between external appearance of NPC and thier inventory. Guards just have this specific sprite and their parameters boosted but posess no PA item at all. In fact all Brotherhood paladiтs who appear to wear a PA won't work as a loot source. ) OFC I'm speaking about the vanilla game, some mods could alter the situation.
AFAIR, there are two option to get the PA in the Fallout. Both are quest-triggered and both are in the lower bunker of the Brotherhood. So, you are at least to get a permission to enter that bunker anyway.
Post edited December 28, 2019 by Schwertz